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【英文标准名称】:StandardPracticeforQualifyingSpectrometersandSpectrophotometersforUseinMultivariateAnalyses,CalibratedUsingSurrogateMixtures
【原文标准名称】:使用代用品混合物校正的多变量分析中使用的分光计和分光光度计鉴定的标准规程
【标准号】:ASTME2056-2004
【标准状态】:现行
【国别】:
【发布日期】:2004
【实施或试行日期】:
【发布单位】:美国材料与试验协会(US-ASTM)
【起草单位】:E13.11
【标准类型】:(Practice)
【标准水平】:()
【中文主题词】:红外线光谱法;分光计;分光光度计;化学分析和试验;定量分析;混合物
【英文主题词】:fluorescencespectroscopy;infraredspectroscopy;molecularspectroscopy;multivariateanalysis;quantitativeanalysis;Ramanspectroscopy;spectrometerqualification;spectrophotometerqualification;ultraviolet-visiblespectroscopy
【摘要】:Thispracticeshouldbeusedbythedeveloperofstandardtestmethodsthatemploysurrogatecalibrations.5.1.1Thispracticeassiststhetestmethoddeveloperinsettinganddocumentingrequirementsforthespectrometer/spectrophotometersthatcanperformthetestmethod.5.1.2Thispracticeassiststhetestmethoddeveloperinsettinganddocumentingspectraldatacollectionandcomputationparametersforthetestmethod.5.1.3Thispracticeassiststhetestmethoddeveloperinselectingamongpossiblemultivariateanalysisproceduresthatcouldbeusedtoestablishthesurrogatecalibration.Thepracticedescribesstatisticalteststhatshouldbeperformedtoensurethatallmultivariateanalysisproceduresthatareallowedwithinthescopeofthetestmethodproducestatisticallyindistinguishableresults.5.1.4ThispracticedescribesstatisticalcalculationsthatthetestmethoddevelopershouldperformonthecalibrationandqualificationdatathatshouldbecollectedaspartoftheILSthatestablishesthetestmethodprecision.Thesecalculationsestablishthelevelofperformancethatspectrometers/spectrophotometersmustmeetinordertoperformthetestmethod.Thispracticedescribeshowthepersonwhocalibratesaspectrometer/spectrophotometercantesttheperformanceofsaidspectrometer/spectrophotometertodetermineiftheperformanceisadequatetoconductthetestmethod.Thispracticedescribeshowtheuserofaspectrometer/spectrophotometercanqualifythespectrometer/spectrophotometertoconductthetestmethod.1.1Thispracticerelatestothemultivariatecalibrationofspectrometersandspectrophotometersusedindeterminingthephysicalandchemicalcharacteristicsofmaterials.AdetaileddescriptionofgeneralmultivariateanalysisisgiveninPracticeE1655.Thisstandardrefersonlytothoseinstanceswheresurrogatemixturescanbeusedtoestablishasuitablecalibrationmatrix.Thispracticespecifiescalibrationandqualificationdatasetrequirementsforinterlaboratorystudies(ILSs),thatis,roundrobins,ofstandardtestmethodsemployingsurrogatecalibrationtechniquesthatdonotconformexactlytoPracticesE1655.Note1--Forsomemultivariatespectroscopicanalyses,interferencesandmatrixeffectsaresufficientlysmallthatitispossibletocalibrateusingmixturesthatcontainsubstantiallyfewerchemicalcomponentsthanthesamplesthatwillultimatelybeanalyzed.WhilethesesurrogatemethodsgenerallymakeuseofthemultivariatemathematicsdescribedinPracticesE1655,theydonotconformtoproceduresdescribedtherein,specificallywithrespecttothehandlingofoutliers.1.2ThispracticespecifieshowtheILSdataistreatedtoestablishspectrometer/spectrophotometerperformancequalificationrequirementstobeincorporatedintostandardtestmethods.Note2--Spectrometer/spectrophotometerqualificationproceduresareintendedtoallowtheusertodetermineiftheperformanceofaspecificspectrometer/spectrophotometerisadequatetoconducttheanalysissoastoobtainresultsconsistentwiththepublishedtestmethodprecision.1.2.1Thespectroscopiesusedinthesurrogatetestmethodswouldincludebutnotbelimitedtomid-andnear-infrared,ultraviolet/visible,fluorescenceandRamanspectroscopies.1.2.2Thesurrogatecalibrationscoveredinthispracticeare:multilinearregression(MLR),principalcomponentsregression(PCR)orpartialleastsquares(PLS)mathematics.ThesecalibrationproceduresaredescribedindetailinPracticesE1655.1.3Forsurrogatetestmethods,thispracticerecommendslimitationsthatshouldbeplacedoncalibrationoptionsthatareallowedinthetestmethod.Specifically,thispracticerecommendsthatthetestmethoddeveloperdemonstratethatal......
【中国标准分类号】:N53
【国际标准分类号】:71_040_50
【页数】:10P.;A4
【正文语种】:


Product Code:SAE AMS4140
Title:Aluminum Alloy Die Forgings, 4.0Cu - 2.0Ni - 0.68Mg (2018-T61), Solution and Precipitation Heat Treated (NONCURRENT Aug 2009)
Issuing Committee:Ams D Nonferrous Alloys Committee
Scope:This specification has been declared “NONCURRENT” by the Aerospace Materials Division, SAE, as of August 2009. It is recommended, therefore, that this specification not be specified for new designs.“NONCURRENT” refers to those materials which may have been widely used previously and which may be required for production or processing of existing designs in the future. The Aerospace Materials Division, however, does not recommend these specifications for future use in new designs.“NONCURRENT” specifications are available from SAE upon request.